Following are some solutions which you can apply, if your Visual Studio is not debugging your silverlight project or if your breakpoints are not hitting properly.

Solution 1:
Use IE (Internet Explorer)

Solution 2:
1-Right click on the Web Application project that comes with Silverlight project
2-From the context menu, chose "Properties". This will open the properties window in the screen.
3-Select web from left menu and scroll down to the end and select checkbox of silverlight.

Solution 3:
Attach the process of silverlight to Internet explorer.

Solution 4:
1-Clean VS Project.
2-Close IDE.
3-Remove all bin and debug folder from project
4-Remove .XAP file from ClientBin folder
5-Start IDE and press F5 to start debugging.

Solution 5:
Try to reset the Visual Studio settings by calling the "devenv /resetsettings" command. This is not recomended untill you have failed all solutions.

Solution 6:
Remove Solution User Options (.suo) file  present in your solution directory.

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This article is related to

C#,.NET,Intermediate,Advanced,VS2010,.Net,Articles,.Net Tutorials,C#,Mobile Development Tutorials,Mobile Developments,Window Phone Tutorials,WP7,WP8,Silverlight, Debugging, Silverlight Breakpoints