For 1 year you have to prepare all basics of .net (c# or vb,sql server,asp.net).

Mainly OOPs concepts. 
a.Abstraction
b.Encapsulation
c.Polymorphism
b.Inheritance
d.Interface
e.Abstraction Vs Interface
f.Abstract Classes
g.Static Classes

Framework basics
a.What is .net framework
b.framework 2.0 vs 3.0 vs 3.5
c.What is CLR & explain
d.What is CTS
f.What is CLS
g.How Garbage Collector Works
h.What is JIT & types of JIT?

ADO.net
a.Dataset
b.Datareader
c.DataAdapter
d.Dataset vs DataReader
e.Dataset Vs DataAdapter

C#
a.Assembly and types
b.Partial classes
c.What is webservices
d.Serialization
e.Single ton
f.Single call

Sql Server
a.Constrains
b.primary key Vs unique key
c.Aggregate Functions
d.Stored Procedure
e.Functions
f.Stored Procedure Vs Functions
G.Vies
h.Triggers
i.Joins & types of Jions
j.Having Vs Where

and many more all are basics only.

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